• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    Chloroalkylthiolcarbamate compounds of the formula: Z-@-S(CH2)nCl (I), wherein Z represents <CHEM> n is an integer of 4 to 10, whereas, when Z is <CHEM> n is an integer of 3 to 10. These compounds are useful as effective herbicides having no harmful effect on the ecosystem, in particular an extremely low toxicity to fish, and can be obtained, for example, by reacting the corresponding thiolcarbamate derivatives with a chloroalkyl halide.
    公开号:SU1181518A3
    申请号:SU813352452
    申请日:1981-11-04
    公开日:1985-09-23
    发明作者:Екояма Сигео；Мисуми Теруюки；Фудзимото Еиносуке；Кобаяси Ютака
    申请人:Асахи Касеи Когио Кабусики Кайся (Фирма)；
    IPC主号:
    专利说明:

    ate

    1 The invention relates to chemical methods for controlling weeds and undesirable vegetation, and in particular to a method for controlling weeds in floodplain crops. At present, strict requirements are imposed on herbicides, which are aimed at eliminating the adverse effects of chemicals on the environment. This is especially true of chemical methods of weed control in rice crops, since in this case it is possible to pollute bodies of water containing living organisms, in particular fish. A known herbicide for controlling weeds in rice crops is molinate (S-hexamethylene-8-ethylthiocarbamate), which is recommended for application to the soil before sowing the culture lj. The known herbicide of the thiocarbamic acid derivatives in N, N-diethyl-S- (3-chloropropyl) thiocarbamate; 2j. However, external herbicides of this type have relatively high toxicity to fish when used at recommended doses. The purpose of the invention is to reduce the toxic effects of herbicides, derivatives of thiocarbamic acids, on fish. This goal is achieved by using as derivatives of thio carbamic acid a compound of the general formula g-C5 (CH2) dC1, where Z is diethylamino, 2-methylpiperidino, or 3,6-dimethyl hexahydry 1H-azepino; , provided that Z is diethyl amino, then 5 or 6; if Z is 2-methylpyridino, then or 5; if Z means 3,6-dimethylhexahide ro-1I-azepino, then 4 or 6, in the amount of 1.5-6 kg / ha. The proposed method makes it possible to effectively fight against weeds in rice crops, not to cause harm to the latter and not to pollute the water reservoir with toxic substances for fish. The compounds of formula (1) can be used in conventional formulations: powders, concentrates. 182 ranulahs, etc. They are prepared by known methods. For comparison, known herbicides recommended for controlling weeds in rice crops are used: compound A (C2H5} 2NCSCH2CH2CH2C1 molinate (- o compound B SI 2 CH2 2 N C3 (CH2) cC1) The derivatives of thiocarbamic acid of the general formula CO are used: 1 3- ( 4-chlorobutyl) -K, K-diztilythiolcarbamate; 2 8- (5-chloropentyl) -, M-diethylthiolcarbamate; 3 5- (6-chlorohexyl) HH Diethylthiolcarbamate; 4 8- (4-chlorobutyl) -2-methylpiperidinetiolcarbamate; 5 S- (5-chloropentyl) -2 - methylpiperidnethiolcarbamate; 6 5 (3-chloropropsh1) -3,6 dimethylhexahydro-1H-azepine-thiolcarbamate; 7 8- (4-chlorobutsh1) -3,6-dimethylphexahydro -1H-azepine-thiolcarbamate; 8 3- (6-chlorhexyl) -3,6-dimethylhexahydro-1H-azepine-thiolcarbamate Example 1. Herbicidal activity against chicken millet and phytotoxicity against race, Special vegetative vessels are filled with rice field soil and four rice seedlings are transplanted into each vessel in the two-leaf stage, then 50 seeds of chicken millet are added to the soil, the vessels are filled with water to a depth of 1 cm and kept in this state until chicken millet reaches stage 1 , 5 sheets (one option) and 3 sheets (second option), By thereafter, the water in which the plants of rice and chicken millet grow, is applied with the active ingredients of the general formula (1) and the known herbicides in the form of an emulsifying concentrate. 31181518 Estimation of herbicidal action and phytotoxicity is carried out in 4. 25 days after treatment according to the following scale 5: 0-degree of damage to plants less than 10% S 1- - 10-29% 2------.- 30-49% Dose, kg / ha Stage 1.5 leaves of the compound millet Herbishad activity (chicken millet) sy de Phyto phyto ni pu 50-69% 70789% more than 90%. Herbicide Activity and phytotoxicity of the active ingredients are given in Table 1. - Table 1 Stage 3 of chicken millet leaves Herbicidal Phytotoxicity (rastate activity of a rice plant) a) (chicken millet)
    Continuation of table 1
    5 5 5 5 5
    Molinat PRI me R 2. Herbicidal action against rice field weeds and phytotoxicity for rice plants Wagner vegetation vessels are filled with rice field soil and four rice sprouts are transplanted into each vessel (in the two-leaf stage having a height of 10 cm). The land containing a large amount of millet seed and the main weeds of the rice floor is brought to the soil surface from 1 to 2 cm deep, and three tubers are planted in the soil. The soil in each jar is kept wet for a week, and then every co.
    5 5 5 5 5
    ABOUT
    ABOUT
    ABOUT
    About the court pour water 5 cm in height and keep flooded. When chicken millet has sprouted to the 2.5-leaf stage, the granules of the active ingredients are added to the water of the rice floor. 25 days after application, the herbicidal action and phytotoxicity of the rice plants is determined. The herbicidal action and phytotoxicity are determined in the same manner as in Example 1. The herbicidal activity and phytotoxicity of the active substances are given in Table. 2. Tables a2
    Molinat
    权利要求:
    Claims (1)
    [1]
    ‘METHOD OF CONTROL OF WEEDS in flooded rice crops by treating these crops with herbicides of thiocarbamic acid derivatives, characterized in that, in order to reduce the subacute toxic effect of herbicides on fish, a compound of the general Formula is used as thiocarbamic acid derivatives
    Z-CS (CH 2 LC1
    II L p . . about where Z is diethylamino, 2-methylpiperidino or 3,6-dimethylhexahydro1P-aepino;
    n = 3-6;
    provided that Z means diethylamino, then η = 4-5 or 6; if Z means 2-methylpyridino, then n = 4 or 5, if Z means 3,6-dimethylhexahydro-1H-azepino, then n = 3.4 or 6, in an amount of 1.5-6 kg / ha.
    类似技术:
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    SU1079163A3|1984-03-07|Herbecidal composition
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    同族专利:
    公开号 | 公开日
    EP0071683B1|1985-03-13|
    BR8107144A|1983-05-10|
    IL64128D0|1982-01-31|
    IL64128A|1985-07-31|
    AT12103T|1985-03-15|
    KR830006895A|1983-10-12|
    EP0071683A1|1983-02-16|
    DE3169285D1|1985-04-18|
    US4400199A|1983-08-23|
    JPS5823602A|1983-02-12|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    US3066020A|1958-08-08|1962-11-27|Stauffer Chemical Co|Method of combating weeds|
    US3305576A|1959-07-10|1967-02-21|Monsanto Co|3-chloropropyl diisopropylthiolcarbamate|
    DE1906050C3|1969-02-07|1979-01-25|Basf Ag, 6700 Ludwigshafen|S-Alkyi-methyl-hexahydro-lHazepine) -1 -carbothiolate|
    FR2095399B2|1970-08-24|1973-06-29|Stauffer Chemical Co|
    US4299765A|1972-08-14|1981-11-10|Stauffer Chemical Company|Herbicidal active sulfoxide compounds|
    FR2196120B1|1972-08-14|1978-03-10|Stauffer Chemical Co|
    DE2333397A1|1973-06-30|1975-01-23|Basf Ag|CARBOTHIOLATE SUBSTITUTED AZEPINE|US4659697A|1983-05-20|1987-04-21|Kentaro Tanaka|Antianaemic composition and a process for producing the same|
    US5288183A|1986-08-18|1994-02-22|Black & Decker Inc.|Self-centering drill bit with pilot tip|
    JPS6430520U|1987-08-18|1989-02-23|
    JPH01181014U|1988-06-10|1989-12-27|
    BR9200508A|1991-02-15|1992-10-20|Kumiai Chemical Industry Co|HERBICIDE COMPOSITION IN THE FORM OF STABLE OR EMULSIFIABLE CONCENTRATE PROPANIL|
    US5639465A|1993-07-19|1997-06-17|Zeneca Limited|Stabilized thiocarbamate herbicides|
    法律状态:
    优先权:
    申请号 | 申请日 | 专利标题
    JP56121325A|JPS5823602A|1981-08-04|1981-08-04|Thiolcarbamate herbicidal composition for paddy field|
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